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  • Mid-1800s, Michael Faraday gave a series of Christmas Lectures for kids at the Royal Institution in London, and one of his favorite subjects to talk about was fire.

  • Faraday was particularly interested in candles, because inside their delicate flames, they hold some amazing lessons on how fire really works.

  • Now, you might have seen fire described like this in chemistry class, but a chemical formula doesn’t explain what fire is anymore than a recipe explains what chocolate chip cookies taste like.

  • The first thing we notice about a candle flame is all those colors.

  • Hot things glow because of black body radiation, which we talked about in our video about the color of the universe.

  • And down at the bottom of the flame, it’s hotter, so it glows blue, and in the middle, it’s cooler, so it glows yellowish-orangish.

  • Inside of that flame, there can be hundreds of chemical reactions taking place.

  • The oxygen in the air and the carbon and hydrogen in the candle don’t do anything on their own.

  • It takes a little outside heat to get things started.

  • Solid fuel is vaporized by the heat and ripped into smaller chunks.

  • This is called pyrolysis, and you can’t have a flame without it.

  • You can sometimes see a dark cone around the wick where there’s no fire.

  • That's where vaporized wax is coming off the candle, but hasn’t started to burn yet.

  • And the hydrocarbons and oxygen in the air slam into each other, and their atoms begin to rearrange.

  • Sometimes electrons in those atoms get into an excited state, and when they come back down again they give off light.

  • That’s why the bottom of the flame glows blue.

  • Not all the carbon in the candle gets converted to CO2, so leftover carbon atoms come together and form tiny particles of soot,

  • which heat up and glow orange and yellow like the hot coals under a grill.

  • This glowing soot is where most of a candle’s light comes from.

  • Eventually, at the tip of the flame, all the soot has burned away, and were left with only carbon dioxide and water floating off into the air.

  • You can investigate all the different parts of a flame for yourself with just a cold piece of metal.

  • Up here, we find water vapor.

  • In the yellow part of the flame, soot.

  • And down just next to the wick, we can even recover unburned wax.

  • Flames look really cool, too. Theyre almost hypnotic

  • Wait, what was I talking about? Oh, oh right, shape.

  • Gravity pulls cool, denser air down, makes hot air rise, and this buoyancy is what gives flames their familiar shape.

  • But if you light a flame in zero-g, say, on the space station, it will look very different.

  • All the chemical and quantum reactions that make a flame glow can only happen where it meets the air,

  • so even though they look like solid cones, candle flames are actually hollow.

  • As long as there’s fuel and oxygen, a flame will burn and burn. Why?

  • It’s not the molecular ripping apart that makes a flame hot.

  • It's the formation of new molecules and new bonds is what creates heat, and that heat drives the chain reaction forward,

  • vaporizing more fuel, slamming more molecules into one another, and making the fire burn on.

  • Our species has been gathering around fire for thousands of years, telling stories and asking questions over a flickering flame.

  • And that's part of what helped make us human in the first place.

  • Stay curious.

Mid-1800s, Michael Faraday gave a series of Christmas Lectures for kids at the Royal Institution in London, and one of his favorite subjects to talk about was fire.

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