of aldehydes and ketones, I just wanted to cover

where the names for those functional groups come from.

So, one way to make aldehydes and ketones

is to oxidize alcohol.

So if we start over here on the left

and we have methanol, we can oxidize that to

methonal over here on the right.

Also called formaldehyde.

And if we analyze the atoms here,

one carbon on the left and one carbon on the right,

one oxygen on the left and one oxygen on the right,

four hydrogens on the left and only two on the right,

so a loss of two hydrogens can convert methonol

to methonal, and so the name of aldehyde

comes from these words here.

So if I write alcohol and then dehydrogenatum,

which refers to the fact that we are losing hydrogens.

If you look closely you can see the name for aldehyde.

If you take the name al from alcohol,

and then this portion of this word,

and then add an e on,

you get the name aldehyde.

So that's the idea.

You can also make ketones.

So if I oxidize this alcohol on the left to propanol,

also called isopropanol or isopropyl alcohol

and then finally rubbing alcohol.

If you oxidize this molecule,

then you get this molecule over here on the right.

So there are three carbons ...

So a three carbon ketone is called a propanone

and of course no one usually calls this propanone.

This is a famous molecule.

This is acetone.

And the old German word for acetone ...

If you spell out the old German word for acetone,

it's easy to see where the word ketone comes from, right?

'Cause if I take this right here and add an e on,

I get ketone.

So just a little bit of insight into those names

which I think is pretty interesting.

In terms of physical properties,

let's use these last two molecules here to

describe boiling points of aldehydes and ketones.

Let's take two propanol over here on the left,

and let's compare the boiling point of

of two propanol to acetone.

So when you are talking about boiling point,

you need to think about intermolecular forces,

so the forces between molecules.

So let's draw out two molecules of isopropanol here.

Let's go ahead and draw one, so we have our

oxygen, we have our hydrogen right here.

Now we know that oxygen is more electronegative

than hydrogen, so the electrons in this bond

are going to be pulled closer to the oxygen

giving the oxygen a partial negative charge

and giving this hydrogen a partial positive charge.

If another molecule of isopropanol comes along,

let's go ahead and show that,

it has the same situation, right?

The oxygen is partially negative

and the hydrogen is partially positive.

We know that opposite charges attract.

Right, so this partial positive charge

is attracted to this partial negative charge,

and this intermolecular force is called hydrogen bonding.

So this is an example of hydrogen bonding,

which we know is between hydrogen and

a very electronegative atom like

fluorine, oxygen, or nitrogen,

and also this hydrogen has to be bonded

to another electronegative atom,

so here we have oxygen.

So this is an example of hydrogen bonding.

The strongest type of intermolecular force.

It takes a lot of energy to pull these molecules apart,

so it takes a lot of heat.

And so the boiling point of isopropanol is relatively high.

The boiling point is approximately 83 degrees Celsius.

So let's compare that situation with acetone.

So let's go ahead and draw out acetone here.

And so here is one molecule of acetone.

If we think about oxygen compared to this

carbonyl carbon here, oxygen is more electronegative,

and so there is going to be a polarization, right?

So the oxygen is going to withdraw electron density

making the oxygen partially negative.

It is taking electron density away from this carbon,

so this carbonyl carbon is partially positive

and so we have a dipole situation.

So this molecule has a dipole moment.

And if we think about another molecule of acetone,

right so another one has the exact same situation, right?

The oxygen is partially negative,

this carbonyl carbon is partially positive,

and so we have an attraction between

this partially negative oxygen

and this partially positive carbon.

So there is an attraction between these two dipoles.

So we call this dipole-dipole interaction,

which is another type of intermolecular force.

Actually hydrogen bonding is just an example

of a very strong dipole-dipole interaction.

So dipole-dipole interactions are not as strong

as hydrogen bonding, so molecules of acetone

aren't attracted to each other as much as

molecules of isopropanol, so it doesn't take

as much energy to pull apart molecules of acetone,

and therefore the boiling point is lower.

The boiling point of acetone is

approximately 56 degrees Celsius.

Both of these temperatures are above room temperature,

but both of these boiling points are above room temperature

so at room temperature and pressure,

two propanol and acetone are both liquids.

Let's look at some other molecules

and let's compare them here.

So we have all molecules with three carbons.

So over here on the left, this is propane.

And the boiling point for propane is approximately

negative 42 degrees Celsius,

so that's well below room temperature.

Room temperature is approximately

between 20 and 25 degrees Celsius,

and so since the boiling point for propane

is well below room temp, the propane is already a gas.

So this state of matter of propane is a gas here.

It terms of intermolecular forces,

the only intermolecular forces holding together

alkanes are London dispersion forces.

So let's go ahead and write that up here.

Next, let's analyze an aldehyde.

Right so a three carbon aldehyde,

one, two, three, so this must be proponal.

The boiling point for proponal is

approximately 50 degrees Celsius.

Once again, higher than room temperature,

so proponal is a liquid.

We have just analyzed acetone.

Our next boiling point is approximately 56 degrees,

and for both proponal and for acetone,

you have the dipole-dipole interaction between molecules.

So we already covered acetone.

The same situation exists for this aldehyde.

So we have a partial negative here and

a partial positive right here,

and so there is going to be dipole-dipole interaction

between molecules of proponal.

So we have once dispersion for our alkane,

and then for our aldehyde and ketone

we have dipole-dipole interaction.

And then finally we have another alcohol.

So instead of two propanol, this is one propanol,

which has a boiling point of approximately 97 degrees.

And one proponal also has of course hydrogen bonding.

So we can see that the boiling points reflect

the type of intermolecular force.

Hydrogen bonding is stronger than dipole-dipole interaction,

and so therefore the boiling points for alcohols

are higher than the boiling points for aldehydes or ketones,

but aldehydes and ketones have a higher boiling point

than alkanes because dipole-dipole interactions

are stronger than London dispersion forces.

So let's look at solubility next.

I just did boiling point,

now lets think about solubility in water.

So let's go ahead and write that.

And once again, let's think about acetone as our example.

And so if we draw this out, here's one molecule

of acetone and I can go ahead and put my lone

pairs of electrons in there on my oxygen,

once again, the oxygen gets a partial negative charge

so the oxygen withdraws some electron density

so it gets a little more negative and

this carbonyl carbon gets a little bit positive,

and so we have this polarized situation

in our acetone molecule.

The thing about solubility and water ...

I'll go ahead and draw the dot structure for water.

We know that water is also polarized here,

so these electrons and this bond

are pulled closer to the oxygen.

So these electrons are pulled closer to the oxygen

giving the oxygen a partial negative,

and giving this hydrogen a partial positive.

So we can see there is going to be an attractive force

between this partial negative and this partial positive.

In terms of intermolecular forces,

we should recognize that as hydrogen bonding.

So this is hydrogen bonding right here.

Because of that, we know that acetone

is going to be soluble in water.

So we have hydrogen bonding.

Now one quick point that I have forgot to mention

in the previous example.

Some people are confused as to why molecules

of acetone can't hydrogen bond with themselves,

so let's go back up here and look at those

two molecules again.

So if I think about the possibility

of hydrogen bonding here,

there is a hydrogen connected to this carbon,

but that's the point.

This hydrogen is connected to a carbon.

It is not connected to something like oxygen,

which is what we had over here.

So hydrogen bonding between molecules of acetone

is not possible because the hydrogen is bonded

to a carbon and not to something like an oxygen.

So even though hydrogen bonding between

molecules of acetone is not possible,

hydrogen bonding between acetone and water is possible,

and so acetone is going to be soluble in water.

So same idea for other small aldehydes and ketones.

Small aldehydes are ketones are going to be

relatively soluble in water.

However, as you increase the chain length,

so if you think about the alkyl groups

attached to either a ketone or an aldehyde,

so let's just look at the alkyl groups here.

As you increase the number of carbons

that are bonded to an aldehyde or ketone,

that increases the non-polar character of the molecule.

So as you increase the chain length,

you make the molecule more non-polar,

and therefore you are going to decrease

the solubility in water.